ISSN 1006-3021 CN11-3474/P
Published bimonthly started in 1979
漓江流域丰水期外源酸对岩溶化学风化碳汇的影响
  
关键词:karst carbon sink  water chemistry  rock chemical weathering  allogenic acids
基金项目:国家自然科学基金项目(编号: 42177075);广西重点研发专项(编号: 2021AB28002);中国地质调查局地质调查项目(编号: DD20190452)
作者单位E-mail
杜文越 中国地质科学院岩溶地质研究所, 自然资源部/广西岩溶动力学重点实验室 duwenyueench@163.com 
王琪 中国地质科学院岩溶地质研究所, 自然资源部/广西岩溶动力学重点实验室
桂林理工大学环境科学与工程学院, 广西环境污染控制理论与技术重点实验室 
 
蒲俊兵 中国地质科学院岩溶地质研究所, 自然资源部/广西岩溶动力学重点实验室  
于奭 中国地质科学院岩溶地质研究所, 自然资源部/广西岩溶动力学重点实验室 yushihydrogeo@163.com 
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摘要:
Effect of Exogenous Acids on the Karst Chemical Weathering and Carbon Sink in Lijiang River during the Wet Season
      To analyze and evaluate the chemical characteristics of water and the influence of allogenic acids on the karst carbon sink of Lijiang River, the main stream sections and tributaries at the catchment were sampled and monitored by combining the Gibbs diagram, ion ratio, Galy model, and isotope characteristic values in April 2020. The results showed that (1) controlled by weathering of carbonate, the hydrochemistry of Lijiang River included HCO3-Ca, and the average equivalence ratio of [Ca2++Mg2+]/[HCO– 3] and [Ca2++Mg2+]/[HCO– 3+SO2– 4+NO– 3] were 0.87, 1.07, respectively. This indicates that the weathering process of carbonate is influenced by the allogenic sulfuric and nitric acid. (2) The carbon sink flux at the final outlet (Yangshuo section) of Lijiang River is 974.86×103 mol·(km2·a)–1. The proportion of carbon fluxes in the total exports fluctuated greatly between different tributaries, with Xiaorong River and Liangfeng River accounting for 1.44% and 35.74%, respectively. The Gantang River and Liangfeng River accounted for 57.04%. (3) The average proportion of CO2 consumption in the tributaries within the basin is 10.02% with significant differences in spatial variation, and is obviously influenced by geological distribution and flow rate of different basins. (4) The DIC contribution rate of chemical weathering process between carbonate and allogenic acid ranged from 13% to 55%. In terms of spatial variation, the DIC contribution rate of Darong River and Taohua River was higher than 50%, whereas the DIC contribution rate of allogenic acid is lower than 13% in the Yangshuo section.
DU Wen-yue,WANG Qi,PU Jun-bing,YU Shi.2022.Effect of Exogenous Acids on the Karst Chemical Weathering and Carbon Sink in Lijiang River during the Wet Season[J].Acta Geoscientica Sinica,43(4):449-460.
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