西藏多龙矿集区铁格隆南铜(金)矿床黄铁矿特征及意义
投稿时间:2022-11-07  修订日期:2023-03-22  点此下载全文
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作者单位邮编
张琪 中国地质大学地球科学与资源学院北京 100083
陈伟* 中国地质科学院矿产资源研究所 
杨欢欢 中国地质科学院矿产资源研究所 
王勤 成都理工大学地球科学学院 
付雪莲 成都理工大学地球科学学院 
李彦波 西藏自治区地质矿产勘查开发局第五地质大队 
辛堂 西藏自治区地质矿产勘查开发局第五地质大队 
李宏伟 西藏自治区地质矿产勘查开发局第五地质大队 
梁鑫娟 成都理工大学地球科学学院 
李社 中铝西藏金龙矿业股份有限公司 
基金项目:国家自然科学基金(42002103)、重点成矿区带铜金等矿产地质调查(DD20230033)、铜(金)锑等紧缺战略性矿产调查与潜力评价(DD20230054)、国家重点研发计划项目:西藏铜多金属资源基地绿色勘查与增储示范(项目编号:2022YFC2905001)
中文摘要:铁格隆南斑岩-浅成低温热液型铜(金)矿床是班公湖-怒江成矿带上最重要的矿床之一。本文以矿床内发育的黄铁矿为主要研究对象,对其开展微量元素、稀土元素和硫同位素分析。依据产出状态,黄铁矿可以分为黄铁矿-1,黄铁矿-2和黄铁矿-3,其中黄铁矿-2与浅成低温热液型矿化相关,黄铁矿-3与斑岩型矿化相关。黄铁矿-1的Au、Ag、Cu、Pb、Zn、Bi的含量最低,黄铁矿-2的Au、Ag、Cu、Pb、Zn、Bi的含量最高。Cu和Ni、Ag和Cu、Cu和Pb、Ag和Pb、Pb和Zn的相关性可作为黄铁矿-2和黄铁矿-3的辨别标志。黄铁矿-1的δ34S值(1.9 ‰)最大;黄铁矿-2和黄铁矿-3的δ34S值在-4.5 ‰~0.3 ‰之间。黄铁矿富集轻稀土,亏损重稀土,具有“右倾”式稀土配分模式,浅部(200-450 m)黄铁矿的轻重稀土分异程度较大,以正铕异常为主,而深部(700-1000 m)黄铁矿轻重稀土分异相对较小,以负铕异常为主。铁格隆南矿床含硫热液运移方向为横向上从ZK1604向东运移,纵向以ZK1604的230-250 m为中心向深部和侧向运移。黄铁矿中高含量的Cu、Au、Ag以及Ag和Cu、Pb和Zn、Cu和Pb、Ag和Pb的正相关性是指示浅成低温型矿化的重要标志,而黄铁矿内Cu和Ni的负相关性是指示斑岩型矿化的标志。
中文关键词:西藏  铁格隆南斑岩-浅成低温热液矿床  黄铁矿  元素地球化学  硫同位素
 
The Characteristic and Significance of Pyrite at Tiegelongnan Cu (Au) Deposit Duolong Ore District, Tibet
Abstract:The Tiegelongnan porphyry-epithermal Cu (Au) deposit is one of the most important deposits in the Bangongco-Nujiang metallogenic belt. Pyrite is widely developed in the Tiegelongnan. The trace element, rare earth element and S isotope analysis of pyrite were carried out in this research. According to the occurrence characteristics, three types of pyrite are revealed including pyrite-1, pyrite-2 related to epithermal mineralization, and pyrite-3 related to porphyry mineralization. Pyrite-1 has the lowest content of Au, Ag, Cu, Pb, Zn and Bi, while pyrite-2 has the highest content of Au, Ag, Cu, Pb, Zn and Bi. The correlation between Cu and Ni, Ag and Cu, Cu and Pb, Ag and Pb, Pb and Zn can be used to distinguish between pyrite-2 and pyrite-3. The value δ34S for pyrite-1 (1.9 ‰) is the highest in the three types of pyrite; The δ34S values for pyrite-2 and pyrite-3 are between -4.5 ‰ and 0.3 ‰. Pyrite is rich in LREE and depleted HREE, and has a "right tilt" pattern of rare earth distribution. The REE differentiation of pyrite in the shallow (200-450 m) is relatively large with positive Eu anomaly, while the REE differentiation of pyrite in the deep (700-1000 m) is small with negative Eu anomaly. The migration direction of sulfur-containing hydrothermal solution in Tiegelongnan deposit is horizontally from ZK1604 to the East, and vertically from 230-250 m of ZK1604 to the deep and lateral. The high content of Cu, Au, Ag in pyrite and the positive correlation between Ag and Cu, Pb and Zn, Cu and Pb, Ag and Pb are important indicators of epithermal mineralization, while the negative correlation between Cu and Ni in pyrite is an indicator of porphyry mineralization.
keywords:Tibet  Tiegelongnan porphyry-epithermal deposit  pyrite  element geochemistry  S isotope
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