| 西藏角东黑云二长花岗斑岩中绿泥石矿物学特征及其地质意义 |
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| 引用本文：李保亮,王立强,何逸飞,何云龙,王勇,高腾,范源.2025.西藏角东黑云二长花岗斑岩中绿泥石矿物学特征及其地质意义[J].地球学报,46(6):1163-1172. |
| DOI：10.3975/cagsb.2024.2024120421 |
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| 基金项目:国家重点研发计划青年科学家项目(编号: 2021YFC2900100)；中国地质科学院矿产资源研究所基本科研业务费项目(编号: KK2306); 中国地质调查局地质调查项目(编号: DD20230360; DD20243483) |
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| 中文摘要:角东钨-铌钽矿区是近年来新发现的与淡色花岗岩-伟晶岩有关的稀有金属矿床。通过野外地质调查, 在矿区发现一处黑云二长花岗斑岩岩体, 并伴有强烈硅化、绿泥石化和孔雀石化。基于详尽的岩相学研究, 对角东矿区黑云二长花岗斑岩中绿泥石进行了电子探针组分分析, 限定其形成的物理化学条件, 并分析斑岩成矿潜力。黑云二长花岗斑岩中绿泥石为典型的铁镁绿泥石, 其形成温度为170~211 ℃, 为黑云母受中-低温流体蚀变所形成。绿泥石的AlIV为1.01~1.30, Fe2+/(Fe2++Mg2+)值为0.642~0.772, Cr/Ti值为0.022~27.125, 氧逸度为–38.6 ~ –34.0, 硫逸度为–13.3 ~ –10.8。相较于西藏典型斑岩型矿床青磐岩化带中绿泥石, 角东黑云二长花岗斑岩中绿泥石具有较高的AlIV、Fe2+/(Fe2++Mg2+)、硫逸度, 中等的温度、Cr/Ti值、氧逸度的特征, 表现出具有一定斑岩铜矿的成矿潜力。 |
| 中文关键词:绿泥石 黑云二长花岗斑岩 斑岩成矿潜力 角东 |
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| Mineralogical Characteristics and Geological Significance of Chlorite in Biotite Monzogranite Porphyry from the Jiaodong Mineralization Area, Tibet |
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| Abstract:The Jiaodong W-Nb-Ta ore district is a recently discovered rare metal deposit associated with leucogranite-pegmatite systems. Field geological surveys identified a biotite monzogranite porphyry intrusion with intense silicification, chloritization, and malachitization. Based on detailed petrographic studies, electron probe microanalysis (EPMA) was conducted on chlorite in the biotite monzogranite porphyry from the Jiaodong district to constrain its physicochemical formation conditions and assess the porphyry mineralization potential. The chlorite in the biotite monzogranite porphyry is identified as typical Fe-Mg chlorite that forms at temperatures ranging from 170 to 211 °C, indicating biotite alteration by medium- to low-temperature fluids. The chlorite is characterized by AlIV values of 1.01–1.30, Fe2+/(Fe2++Mg2+) ratios of 0.642–0.772, Cr/Ti ratios of 0.022–27.125, oxygen fugacity (fO2) values ranging from ?38.6 to ?34.0, and sulfur fugacity (fS2) values ranging from ?13.3 to ?10.8. Compared with chlorite from the propylitic alteration zones of typical porphyry deposits in Tibet, the chlorite in the biotite monzogranite porphyry from the Jiaodong district is characterized by higher AlIV, Fe2+/(Fe2++Mg2+), and sulfur fugacity, as well as moderate temperature, Cr/Ti ratios, and oxygen fugacity. These characteristics suggest a certain potential for porphyry copper mineralization. |
| keywords:chlorite biotite monzogranite porphyry metallogenic potential of porphyry Jiaodong |
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