江西宁都坎田萤石矿床稀土元素地球化学特征及其指示意义
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引用本文:游超,王春连,刘殿鹤,余小灿,颜开,刘思晗,周博文.2022.江西宁都坎田萤石矿床稀土元素地球化学特征及其指示意义[J].地球学报,43(3):359-370.
DOI:10.3975/cagsb.2022.040101
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游超 中国地质大学(武汉)地质调查研究院
中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室 
youchao126418@163.com 
王春连 中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室 wangchunlian312@163.com 
刘殿鹤 中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室
北京大学地球与空间科学学院 
 
余小灿 中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室  
颜开 中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室  
刘思晗 中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室
昆明理工大学国土资源工程学院 
 
周博文 中国地质科学院矿产资源研究所, 自然资源部成矿作用与资源评价重点实验室
昆明理工大学国土资源工程学院 
 
基金项目:中央级公益性科研院所基本科研业务费专项(编号: KK2005);中国地质调查局地质调查项目(编号: DD20190816; DD20190606; DD20221684)
中文摘要:赣南地区萤石资源丰富, 坎田萤石矿位于赣南地区的兴国—宁都萤石成矿带上, 矿体赋存于晚侏罗世黑云母花岗岩内。本文结合研究区的区域地质背景, 对江西宁都坎田萤石矿床的萤石及围岩进行了稀土元素地球化学特征研究, 以探讨坎田萤石矿床的成矿流体来源和矿床成因。其研究结果表明, 萤石的稀土元素总量为34.11×10–6~78.12×10–6, 属于轻稀土富集型, 稀土元素配分曲线形态基本一致; 围岩的稀土元素总量为94.14×10–6~175.72×10–6, 其配分模式与萤石具有相似同步性, 且萤石与围岩具有相近的Sm/Nd比值, 均表明萤石的成矿流体来源与围岩密切相关。结合前人在赣南地区对萤石气液包裹体进行氢氧同位素特征的研究, 认为成矿流体主要来源于大气降水, 成矿物质Ca和F元素主要来自于大气降水对燕山早期的黑云母花岗岩的淋滤和萃取。通过研究区的地质背景、萤石的强烈负Eu异常特征以及Tb/Ca-Tb/La关系图, 认为研究区萤石矿属于还原环境下的中低温热液充填型萤石矿床。
中文关键词:萤石矿  稀土元素  成矿流体  矿床成因  江西宁都
 
REE Geochemistry of Fluorite from Kantian Fluorite Deposit and Its Geological Implications in Ningdu Area, Jiangxi Province
Abstract:The Kantian fluorite deposit is located in the Xingguo–Ningdu fluorite metallogenic belt in southern Jiangxi Province, where fluorite resources are abundant. The orebody occurs in Late Jurassic biotite granite. Based on the regional geological background of the study area, the REE geochemical characteristics of the fluorite and surrounding rock of the Kantian fluorite deposit in Ningdu, Jiangxi Province, were studied to evaluate the source of the ore-forming fluid and genesis of the deposit. The total REE concentrations of fluorites range from 34.11×10–6 to 78.12×10–6, the chondrite normalized REE distribution pattern is characterized by relative enrichment of LREEs, and the LREEs have similar distribution patterns. The total REE concentrations of wall rocks range from 94.14×10–6 to 175.72×10–6, the REE distribution patterns of fluorites and wall rocks have similar synchronization, and the Sm/Nd ratios of fluorite and surrounding rock are similar, indicating that the source of the ore-forming fluid of the fluorite was closely related to the surrounding rock. By considering these results in combination with previous studies on hydrogen and oxygen isotope characteristics of fluorite gas-liquid inclusions in southern Jiangxi, it was concluded that the ore-forming fluids were mainly derived from meteoric precipitation and that the ore-forming elements Ca and F were mainly derived from precipitation leaching and extraction from biotite granites of the early Yanshanian. Based on the geological background, strong negative Eu anomalies of fluorite, and the Tb/Ca-Tb/La relationship diagram in the study area, it was determined that the fluorite ore in the study area is a middle-low temperature hydrothermal filling fluorite deposit formed under a reductive environment.
keywords:fluorite ore  REE  ore-forming fluid  genesis of mineral deposit  Ningdu County, Jiangxi Province
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