四川里庄稀土矿床岩浆碳酸岩的地球化学 |
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引用本文:田世洪,张桂兰,侯增谦,丁悌平,邹天人,袁忠信,白鸽,谢玉玲.2005.四川里庄稀土矿床岩浆碳酸岩的地球化学[J].地球学报,26(z1):151-155. |
DOI:10.3975/cagsb.2005.s1.50 |
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基金项目:本文得到国家重点基础研究发展规划项目(编号:2002CG412610和G1999043211)和国家杰出青年基金项目(编号:40425014)联合资助。 |
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中文摘要:里庄稀土矿床位于四川冕宁县西南方向49 km,为侵位于碱性杂岩体中的碳酸岩脉状矿床。本文从稀土元素地球化学和同位素地球化学的角度探讨了碳酸岩与地幔过程之间的关系。研究表明,碳酸岩的∑REE为(9236.2~5943.6)×10-6,为LREE富集型,与典型岩浆碳酸岩特征相似;碳酸岩的C、O同位素组成非常稳定,其δ13CV-PDB和δ13OV-SMOW,分别为-3.9‰~-5.3‰和8.7‰~11.9‰,均落在“原生碳酸岩”的C、O同位素组成范围之内;碳酸岩的Pb、Sr同位素组成比较均一,其87Sr/86Sr,206Pb/204Pb,207Pb/204Pb,208Pb/204Pb分别为0.706305~0.706997、18.197~18.220、15.601~15.604、38.401~38.434,与EMⅠ型地幔源区的同位素组成基本一致。所有这些特征均表明岩石来自交代富集地幔源区。 |
中文关键词:岩浆碳酸岩 稀土元素 同位素地球化学 EMI 四川里庄稀土矿床 |
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Geochemistry of Carbonatites in the Lizhuang REE Deposit, Sichuan Province |
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Abstract:The Lizhuang REE deposit, located about 49 km southwest of Mianning County, Sichuan Province, is a carbonatite veintype deposit hosted in alkali complex rocks. In order to find out the relationship between the carbonatites and the mantle processes, the authors made a systematic study of REE geochemistry and C, O, Sr, and Pb isotopes. The ∑REE contents of carbonatites range from 8393×10-6 to 8402×10-6,with smooth right-dipping distribution patterns that are similar to those of the well-established magmatic carbonatite. The C and O isotopic compositions of the calcite samples from the carbonatite stocks in the Lizhuang REE deposit vary in a very limited range, with the δ13CV-PDB and δ13OV-SMOW values varying in the range of -3.9‰~5.3‰ and 8.7‰~11.9‰, respectively. They are fallen into the range of the "primary igneous carbonatites". The Sr and Pb isotopic compositions of the calcite samples from the carbonatite in the Lizhuang REE deposit are relatively constant, with the 87Sr/86Sr, 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values varying in the range of 0.706305±0.706997, 18.197~18.220, 15.601~15.604, and 38.401~38.434, respectively. The similarity of Sr and Pb isotopic compositions of the carbonatite with those of EMⅠ suggests an enriched mantle source for the mineralization of rare earth elements. All of these data suggest that the rocks were derived from the metasomatic enriched mantle. |
keywords:carbonatite REE geochemistry isotope geochemistry EMⅠ Lizhuang REE deposit in Sichuan Province |
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