湖北恩施地区硒地质地球化学环境背影
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引用本文:张光弟,葛晓立,张绮玲,罗代洪,刘新平,Fordyce F.M.,毛大钧,苏宏灿.1998.湖北恩施地区硒地质地球化学环境背影[J].地球学报,19(1):59-67.
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作者单位
张光弟 中国地质科学院矿床地质研究所 
葛晓立 中国地质科学院岩矿测试技术研究所 
张绮玲 中国地质科学院矿床地质研究所 
罗代洪 中国地质科学院岩矿测试技术研究所 
刘新平 中国地质科学院岩矿测试技术研究所 
Fordyce F.M. British Geological Survey 
毛大钧 恩施州卫生防疫站 
苏宏灿 恩施州妇幼保健医院 
中文摘要:我国湖北省恩施州存在一个高Se环境区和一个低Se环境区。它们曾分别暴发流行过人体Se中毒和克山病。在高Se区的地层岩石中共有5个含Se层位,因而本区在各个地质历史时期都存在高Se地质背景,但Se中毒只发生于下二叠统茅口组上段和吴家坪组控制的范围内。富Se的二叠系岩石中以硅质炭质页岩含Se最高(平均247.72×10-6),其次为含炭硅质岩(平均52.4×10-6),最低为硅质白云岩(平均3.13×10-6)。Se质量分数随上述岩石类型降低的趋势与这些岩石中有机炭浓度依次降低有关。高Se区同一地层岩石在不同地点发育的土壤总Se质量分数和水溶性Se质量分数的分布存在明显的差异。根据这种差异可划分出3种土壤Se的分布类型,并据此提出进行高Se中毒危险区的地球化学预测。高Se与低Se土壤出露范围的大小决定于其源岩所处的地质构造、岩石性质与产状和地形坡度综合作用的结果。富Se岩石和缺Se岩石各自产于褶皱的两翼和向斜核部。产状平缓且与坡度方向一致,呈面状大面积出露,其派生的土壤Se影响范围较大。在挤压褶皱两翼的富Se岩层产状陡,呈狭窄条带出露,其派生的土壤Se影响范围取决于搬运介质的性质、强度以及所处的地形条件。
中文关键词:Se分布  地质地球化学背景
 
Selenium Geological and Geochemical Environmental Background in Enshi, Hubei
Abstract:There are a Se_rich area and a Se_poor area in Enshi, Hubei province, China. Human selenosis and KD cases were reported in the Se_rich area and in the Se_poor area respectively. Five Se_rich rock formations exist in the Se_rich area, but selenosis cases were only found in the areas where the Upper Maokou Formation(P 1 m ) and Wujiaping Formation(P 2 w ) of the Permian system emerge. The siliceous and carbonaceous shales of Permian system have high selenium content swith an average of 247.72×10 -6 , carbon silicalite is less abundant averaging 52.4×10 -6 , and siliceous dolomite has the lowest selenium content (3.13×10 -6 ). The selenium decreasing along with the above_mentioned various rocks is directly influenced by the decreasing of their organic carbon. In the Se_poor area, purple sandstone and mudstone, which are lack of the organic carbon material collecting selenium, have a very low selenium content. The large or small exposure areas of both Se_rich and Se_poor soils,are controlled by a comperehensive result of structure, lithologic characters and slope of landform and so on. Se_rich rocks are located in either the flanks or synclinal core. If the dip angles of rock formations are smaller and consistent with slope of landform, the exposed area of the rock will be large and the Se_rich soil derived from the rock will influence widely. If the Se_rich rock formations in flanks of compression folds have steep dip angles and narrow area of outcrop, the distribution of the soil derived from the rock is controlled by the nature and intense of the transporting media and the landscope.
keywords:selenium distribution  geological and geochemical background
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