ISSN 1006-3021 CN11-3474/P
Published bimonthly started in 1979
原位制备铝土矿基Li+吸附材料及其提锂应用
投稿时间:2024-10-15  修订日期:2024-10-26
关键词:Bauxite  In-situ  Adsorbent  Brine  Lithium adsorption
基金项目:本文得到西藏自治区重大科技专项“矿产资源--优势资源绿色利用”项目(编号:XZ202201ZD0004G)及课题1“ 西藏高原条件下锂盐湖原卤提锂方法研究”(XZ202201ZD0004G01)资助.
作者单位邮编
丁涛 中国地质科学院矿产资源研究所自然资源部盐湖资源与环境重点实验室 100037
钱程* 眉山职业技术学院 
李玉彬 西藏大学工学院 
王鑫磊 中国地质科学院矿产资源研究所自然资源部盐湖资源与环境重点实验室 
郑绵平 中国地质科学院矿产资源研究所自然资源部盐湖资源与环境重点实验室 
乜贞 中国地质科学院矿产资源研究所自然资源部盐湖资源与环境重点实验室 
王丹 眉山职业技术学院 
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摘要:
In-situ preparation of bauxite based Li+ adsorption materials and their adsorption properties for Li+ in brine
      In this investigation, natural bauxite (NBX) was used as raw material to prepare bauxite based Li+ adsorbent (SATA-AIS-LDH-BX) by solid phase alkali-thermal acid-in situ method, and the adsorption properties of the material to simulated Li+ solution and actual Li+ brine were investigated. The adsorbents were characterized by SEM, EDS, XRD, FT-IR and XPS. The results showed that LiCl?2Al(OH)3?nH2O was present in the adsorbent structure .SATA-AIS-LDH-BX had better adsorption capacity in neutral environment. In the presence of Na+, K+, Ca2+ and Mg2+, it had certain selective adsorption capacity for Li+. The adsorption kinetics and adsorption isothermal model were consistent with the second-order kinetics model and Langmuir model. The saturated adsorption capacity was 1.54 mg/g at 298K. In the actual brine adsorption, when the solid-liquid ratio is 1.8g /25 mL, the adsorption rate of SATA-AIS-LDH-BX for Li+ in brine was 81.64%, and after 5 cycles of elution and adsorption, the adsorption capacity of SATA-AIS-LDH-BX for Li+ was reduced by 12.26%, indicated that the good regeneration performance of the material.
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